Selective Cleavage of SCO by Transition Metal Complexes
نویسندگان
چکیده
منابع مشابه
Activation of Alkanes by Transition Metal Complexes
The data are presented for catalytic H-D exchange of alkanes with protic solvents and some other reactions of alkanes in the presence of transition metal complexes, particularly Pt(II). In Pt(II) chloride solutions the activity of Pt-containing species towards alkanes is in the order S2PtC12> SPtC13> PtC14 (S—solvent). Ligands with properties of soft bases (CN, CNS, PPh etc.) decrease the rate ...
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Tertiary silane 1H , 2-[(diphenylsilyl)methyl]-6-methylpyridine, reacts with tris(pentafluorophenyl)borane (BCF) to form the intramolecular pyridine-stabilized silylium 1+ -HBCF. The corresponding 2-[(diphenylsilyl)methyl]pyridine, lacking the methyl-group on the pyridine ring, forms classic N(py)→B adduct 2H -BCF featuring an intact silane Si-H fragment. Complex 1+ -HBCF promotes cleavage of t...
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ژورنال
عنوان ژورنال: ANU Undergraduate Research Journal
سال: 2012
ISSN: 1836-5531,1837-2872
DOI: 10.22459/aurj.04.2012.03